The Role of Polyfunctionality in the Formation of [Ch]Cl-carboxylic acid-based DES
Emanuel Almeida Crespo, Liliana Silva, Mónia Andreia Rodrigues Martins, Mark Bulow, Olga Ferreira, Gabriele Sadowski, Christoph Held, Simão P. Pinho and João A.P. Coutinho
Design and characterization of sugar-based deep eutectic solvents using COSMO-RS
Liliana P. Silva, Luis Fernández, João H.F. Conceição, Mónia Andreia Rodrigues Martins, Adriel Sosa, Juan Ortega, Simao P. Pinho, and João A.P. Coutinho
Aqueous Biphasic Systems Composed of Cholinium Chloride and Polymers as Effective Platforms for the Purification of Recombinant Green Fluorescent Protein
Nathalia Vieira dos Santos, Margarida Martins, Valéria de Carvalho Santos-Ebinuma, Sónia P.M. Ventura, João A.P. Coutinho, Sandro Roberto Valentini and Jorge Fernando Brandão Pereira
Proceedings of 3rd Path Spring Workshop: Multibiorefinery
João A. P. Coutinho, Mara G. Freire, Sónia P. M. Ventura, Pedro J. Carvalho, Armando J. D. Silvestre
(2018) . DOI:
Tunable Hydrophobic Eutectic Solvents Based on Terpenes and Monocarboxylic Acids
Mónia Andreia Rodrigues Martins, Emanuel Almeida Crespo, Paula V.A. Pontes, Liliana P. Silva, Mark Bülow, Guilherme J. Maximo, Eduardo Augusto Caldas Batista, Christoph Held, Simão P. Pinho and João A.P. Coutinho
Odd-Even Effect on the Formation of Aqueous Biphasic Systems Formed by 1-alkyl-3-methylimidazolium chloride Ionic Liquids and Salts
Diana C. V. Belchior, Tânia E. Sintra, Pedro J. Carvalho, Mário R. C. Soromenho, José M. S. S. Esperança, Sónia P. M. Ventura, Robin D. Rogers, João A. P. Coutinho, and Mara G. Freire
The Journal of Chemical Physics 148 (2018) 193842. DOI: 10.1063/1.5012020
Separation of Phenolic Compounds by Centrifugal Partition Chromatography
João H. P. M. Santos, Mafalda R. Almeida, Cláudia I. R. Martins, Ana C. R. V. Dias, Mara G. Freire, João A. P. Coutinho and Sónia P. M. Ventura
Mechanism of Ionic Liquid-Based Acidic Aqueous Biphasic Systems Formation
Nicolas Schaeffer, Helena Passos, Matthieu Gras, Vijetha Mogilireddy, João P Leal, German Perez-Sanchez, José R. B. Gomes, Isabelle Billard, Nicolas Papaiconomou and João A. P. Coutinho
Physical Chemistry Chemical Physics 20 (2018) 9838-9846 . DOI: 10.1039/C8CP00937F
Measurement and Modeling of Isobaric Vapor–Liquid Equilibrium of Water + Glycols
Naima Chouireb, Emanuel A. Crespo, Luís M. C. Pereira, O. Tafat-Igoudjilene, Lourdes F. Vega , João A. P. Coutinho and Pedro J. Carvalho
Mechanisms Ruling the Partition of Solutes in Ionic-Liquid-Based Aqueous Biphasic Systems – the Multiple Effects of Ionic Liquids
Helena Passos, Teresa B. V. Dinis, Emanuel V. Capela, Maria V. Quental, Joana Gomes, Judite Resende, Pedro P. Madeira, Mara G. Freire and João A. P. Coutinho
In situ Purification of Periplasmatic L-asparaginase by Aqueous Two Phase Systems with Ionic Liquids (ILs) as Adjuvants
João H. P. M. Santos, Juan C. F. Santos, Giovanna P. Meneguetti, Carlota O. Rangel-Yagui, João A. P. Coutinho, Michele Vitolo, Sónia P. M. Ventura, Adalberto Pessoa Jr.
Journal of Chemical Technology and Biotechnology 93 (2018) 1871-1880. DOI: 10.1002/jctb.5455
Stimuli Responsive Ion Gels Based on Polysaccharides and Other Polymers Prepared Using Ionic Liquids and Deep Eutectic Solvents
Kamalesh Prasad, Dibyendu Mondal, Mukesh Sharma, Mara G. Freire, Chandrakant Mukesh, Jitkumar Bhatt
Purification of Clavulanic Acid Produced by Streptomyces clavuligerus Via Submerged Fermentation Using Polyethylene Glycol/Cholinium Chloride Aqueous Two-Phase Systems
Paweł Panas, Camila Lopes, Marcel O.Cerri, Sónia P.M.Ventura, Valéria C.Santos-Ebinuma and Jorge F.B. Pereira
Deep Eutectic Solvents as Efficient Media for the Extraction and Recovery of Cynaropicrin from Cynara cardunculus L. Leaves
Emanuelle L. P. de Faria, Rafael S. do Carmo, Ana Filipa M. Cláudio, Carmen S. R. Freire, Mara G. Freire and Armando J. D. Silvestre
International Journal of Molecular Sciences 18 (2017) 2276-2285. DOI: 10.3390/ijms18112276
Characterization and Modeling of the Liquid Phase of Deep Eutectic Solvents Based on Fatty Acids/Alcohols and Choline Chloride
Emanuel A. Crespo, Liliana P. Silva, Mónia A. R. Martins, Luis Fernandez, Juan Ortega, Olga Ferreira, Gabrielle Sadowski, Christoph Held, Simão P. Pinho, and João A. P. Coutinho
Industrial and Engineering Chemical Research 56 (2017) 12192–12202. DOI: 10.1021/acs.iecr.7b02382
A Triple Salting-Out Effect is Required for the Formation of Ionic-Liquid-Based Aqueous Multiphase Systems
Helena Passos, Sara H. Costa, Ana M. Fernandes, Mara G. Freire, Robin D. Rogers, João A. P. Coutinho
Angewandte Chemie International Edition 56 (2017) 15058-15062. DOI: 10.1002/anie.201705704
Using Ionic Liquids to Tune the Performance of Aqueous Biphasic Systems Based on Pluronic L-35 for the Purification of Naringin and Rutin
Francisca A. e Silva, Rui M.C. Carmo, Andreia P.M. Fernandes, Mariam Kholany, João A.P. Coutinho, and Sonia P.M. Ventura
Long-Term Protein Packaging in Cholinium-Based Ionic Liquids: Improved Catalytic Activity and Enhanced Stability of Cytochrome C Against Multiple Stresses
Meena Bisht, Dibyendu Mondal, Matheus M Pereira, Mara G Freire, Pannuru Venkatesu and João A. P. Coutinho
Primary and Secondary Aqueous Two-Phase Systems Composed of Thermo Switchable Polymers and Bio-Derived Ionic Liquids
Cher Pin Song, Ramakrishnan Nagasundara Ramanan, R. Vijayaraghavan, Douglas R. MacFarlane, Eng-Seng Chan, João A.P. Coutinho, Luis Fernandez, Chien-Wei Ooi
Aqueous Solutions of Surface-Active Ionic Liquids: Remarkable Alternative Solvents to Improve the Solubility of Triterpenic Acids and Their Extraction From Biomass
Emanuelle L. P. de Faria, Selesa V. Shabudin, Ana Filipa M. Cláudio, Mónica Valega, Fernando MJ Domingues, Carmen Sofia Rocha Freire, Armando J.D. Silvestre, and Mara G. Freire
New Experimental Data and Modeling of Glymes: Toward the Development of a Predictive Model for Polyethers
Pablo Navarro, Emanuel A. Crespo, João M. L. Costa, Fèlix Llovell, Julián García, Francisco Rodríguez Pedro J. Carvalho, Lourdes F. Vega and João A. P. Coutinho
Optimization and Comparison of Maceration and Microwave Extraction Systems for the Production of Phenolic Compounds from Juglans regia L. for the Valorization of Walnut Leaves
Vanessa Vieira, Miguel A. Prieto, Lillian Barros, João A.P. Coutinho, Olga Ferreira, Isabel C.F.R. Ferreira
Enhanced Extraction and Biological Activity of 7-hydroxymatairesinol obtained from Norway Spruce knots using Aqueous Solutions of Ionic Liquids
Ana M. Ferreira, Eduarda Morais, Ana Cláudia Leite, Aminou Mohamadou, Bjarne Holmbom, Thomas Holmbom, Bruno Neves, João A. P. Coutinho, Mara. G. Freire and Armando Silvestre
Measurement and PC-SAFT Modeling of Solid-Liquid Equilibrium of Deep Eutectic Solvents of Quaternary Ammonium Chlorides and Carboxylic Acids
Paula V.A. Pontes, Emanuel A. Crespo, Mónia A.R. Martins, Liliana P. Silva, Catarina M.S.S. Neves, Guilherme J. Máximo, Miriam Dupas Hubinger, Eduardo A.C. Batista, Simão P. Pinho, João A.P. Coutinho, Gabriele Sadowski, Christoph Held
Temperature Dependency of Aqueous Biphasic Systems: an Alternative Approach for Exploring the Differences Between Coulombic-Dominated Salts and Ionic Liquids
Francisca A. e Silva, Jorge F. B. Pereira, Kiki A. Kurnia, Sónia P.M. Ventura, Artur M. S. Silva, Robin D. Rogers, João A. P. Coutinho and Mara G. Freire
Evaluation of the Solvent Structural Effect Upon the Vapor–liquid Equilibrium of [C4C1im][Cl] + Alcohols
Naima Chouireb, Imran Khan, Emanuel A. Crespo, Mariana B. Oliveira, Fèlix Llovell, Lourdes F. Vega, O. Tafat-Igoudjilene, A. Ait Kaci, Luís M.N.B.F. Santos, Pedro J. Carvalho and João A.P. Coutinho
New Measurements and Modeling of High Pressure Thermodynamic Properties of Glycols
Emanuel A. Crespo, João M. L. Costa, Zulhakimiali B. M. A. Hanafiah, Kiki A. Kurnia, Mariana B. Oliveira, Fèlix Llovell, Lourdes F. Vega, Pedro J. Carvalho and João A. P. Coutinho
Volumetric and acoustical properties of aqueous mixtures of N-methyl-2- hydroxyethylammonium butyrate and N-methyl-2-hydroxyethylammonium pentanoate at T = (298.15 to 333.15) K
Yang Li, Eduardo J.P. Figueiredo, Mário J.S.F. Santos, Jaime B. Santos, Nieves M.C. Talavera-Prieto, Pedro J. Carvalho, Abel G.M. Ferreira and Silvana Mattedi
Proceedings of 1st Path Spring Workshop: Aqueous Biphasic Systems.
João A.P. Coutinho, Mara G. Freire, Sónia P.M. Ventura
(2016)
Heterologous Expression and Purification of Active L-asparaginase I of Saccharomyces cerevisiae in Escherichia coli Host.
João H. P. M. Santos, Iris M. Costa, João V. D. Molino, Mariana S. M. Leite, Marcela V. Pimenta, João A. P. Coutinho, Adalberto Pessoa Jr, Sónia P. M. Ventura, André M. Lopes, Gisele Monteiro.
Ionic-Liquid-Based Aqueous Biphasic Systems. Fundamentals and Applications
Edited by Mara G. Freire Chapter authors: Mara G. Freire, José N. Canongia Lopes, André M. da Costa Lopes, Rafał Bogel-Łukasik, Rahmat Sadeghi, Mohammed Taghi Zafarani-Moattar, Sholeh Hamzehzadeh, Rupali K. Desai, Mathieu Streefland, Rene H. Wijffels, Michel H. M. Eppink, María J. Trujillo-Rodríguez, Verónica Pino, Juan H. Ayala, Milen G. Bogdanov, Ivan Svinyarov, Isabelle Billard, Kamalakanta Behera, Rewa Rai, Shruti Trivedi, Siddharth Pandey, Jorge F. B. Pereira, Rudolf Deutschmann, Robin D. Rogers, Sónia P. M. Ventura, João A. P. Coutinho.
Modeling the Vapor–Liquid Equilibria and Water Activity Coefficients of Alternative Refrigerant-Absorbent Ionic Liquid–Water Pairs for Absorption Systems
M.B. Oliveira, E.A. Crespo, F. Llovell, L.F. Vega, J.A.P. Coutinho
Why are Some Cyano-Based Ionic Liquids Better Glucose Solvents than Water?
Marta Batista, Helena Passos, Bruno Henriques, Edward J. Maginn, Simão P. Pinho, Mara G Freire, José R. B. Gomes and João A.P. Coutinho
Physical Chemistry Chemical Physics 18 (2016) 18958-18970. DOI: 10.1039/C6CP02538B
Solubility and Solvation of Monosaccharides in Ionic Liquids
Ana Rita Ribeiro Teles, Teresa B. V. Dinis, Emanuel V. Capela, Luis Belchior Santos, Simão P. Pinho, Mara G Freire and Joao A.P. Coutinho
Physical Chemistry Chemical Physics 18 (2016) 19722-19730. DOI: 10.1039/C6CP03495K
Alcohols as Molecular Probes in Ionic Liquids: Evidence for Nanostructuration
Inês C. M. Vaz, Arijit Bhattacharjee, Marisa A.A. Rocha, João A.P. Coutinho, Margarida Bastos and Luis Belchior Santos
Physical Chemistry Chemical Physics 18 (2016) 19267-19275. DOI: 10.1039/C6CP03616C
Influence of Nanosegregation on the Surface Tension of Fluorinated Ionic Liquids
Andreia Luís, Karina Shimizu, João M. M. Araújo, Pedro J. Carvalho, José A. Lopes-da-Silva, José N. Canongia Lopes, Luís Paulo N. Rebelo, João A. P. Coutinho, Mara G. Freire and Ana B. Pereiro
DFT Study of the Reaction Mechanisms of Carbon Dioxide and Its Isoelectronic Molecules CS2 and OCS Dissolved in Pyrrolidinium and Imidazolium Acetate Ionic Liquids
Yann Danten, Maria Isabel Cabaco, João A.P. Coutinho, Noel Pinaud, and Marcel Besnard
Recovery of Capsaicin from Capsicum frutescens by Applying Aqueous Two-Phase Systems Based on Acetonitrile and Cholinium-Based Ionic Liquids
Poliane Lima Santos, Lana Naiadhy Silva Santos, Sónia Patrícia Marques Ventura, Ranyere Lucena de Souza, João Araújo Pereira Coutinho, Cleide Mara Faria Soares, Álvaro Silva Lima
Lipase Production and Purification from Fermentation Broth Using Ionic Liquids - Opportunities and Challenges. In Ionic Liquids in Lipid Processing and Analysis
(Eco)toxicity and Biodegradability of Protic Ionic Liquids
Maria V.S. Oliveira, Bruna T. Vidal, Claudia M. Melo, Rita de C.M. de Miranda, Cleide M.F. Soares, João A.P. Coutinho, Sónia P.M. Ventura, Silvana Mattedi, Álvaro S. Lima
High Pressure Solubility of CH4, N2O and N2 in 1-butyl-3-methylimidazolium dicyanamide: Solubilities, Selectivities and soft-SAFT Modeling
Luís M.C. Pereira, Vânia Martins, Kiki Adi Kurnia, Mariana B. Oliveira, Ana M.A. Dias, Felix Llovell, Lourdes F. Vega, Pedro J. Carvalho, João A.P. Coutinho
Structural Insights Into the Effect of Cholinium-Based Ionic Liquids on the Critical Micellization Temperature of Aqueous Triblock Copolymers
Imran Khan, Reddicherla Umapathi, Márcia C. Neves, João A. P. Coutinho and Pannuru Venkatesu
Physical Chemistry Chemical Physics 18 (2016) 8342-8351. DOI: 10.1039/c5cp07079a
Fatty Acids’ Profiles as Indicators of Stress Induced by of a Common Herbicide on Two Marine Bivalves Species: Cerastoderma edule (Linnaeus, 1758) and Scrobicularia plana (da Costa, 1778)
A.M.M. Gonçalves, A.F. Mesquita, T. Verdelhos, J.A.P. Coutinho, J.C. Marques, F. Gonçalves
Evaluating Self-buffering Ionic Liquids for Biotechnological Applications
Sze Ying Lee, Filipa A. Vicente, Francisca A. e Silva, Tânia E. Sintra, Mohamed Taha, Ianatul Khoiroh, João A. P. Coutinho, Pau Loke Show and Sónia P. M. Ventura
Densities, Viscosities and Derived Thermophysical Properties of Water-Saturated Imidazolium-Based Ionic Liquids
Mónia A.R. Martins, Catarina M.S.S. Neves, Kiki A. Kurnia, Pedro J. Carvalho, Marisa A.A. Rocha, Luís M.N.B.F. Santos, Simão P. Pinho and Mara G. Freire
Lipase Production and Purification from Fermentation Broth Using Ionic Liquid
Sónia P. M. Ventura and João A. P. Coutinho
Ionic Liquids in Lipid Processing and Analysis: Opportunities and Challenges(2016) 59-97
Extração e Purificação de Produtos de Valor Acrescentado Utilizando Sistemas Aquosos Bifásicos Constituídos por Líquidos Iónicos
Ana M. Ferreira, Mara G. Freire
Química - Boletim da SPQ 139 (2015) 23-34
Ionic Liquids for Better Separation Processes: Aqueous Biphasic Systems Based on Ionic Liquids for Extraction, Concentration and Purification Approaches
Isabel M. Marrucho, Mara G. Freire
Part of the series Green Chemistry and Sustainable Technology (2015) 91-119. DOI: 10.1007/978-3-662-48520-0_5
Thermophysical Properties of Glycols and Glymes
Pedro J. Carvalho, Cristofe H. G. Fonseca, Maria-Luísa C. J. Moita, Ângela F. S. Santos, and João A. P. Coutinho
Enhancing the Antioxidant Characteristics of Phenolic Acids by Their Conversion into Cholinium Salts
Tânia E. Sintra, Andreia Luís, Samuel N. Rocha, Ana I. M. C. Lobo Ferreira, Fernando Gonçalves, Luís M. N. B. F. Santos, Bruno M. Neves, Mara G. Freire, Sónia P. M. Ventura and João A. P. Coutinho
Hydrogen-Bond Acidity of Ionic Liquids: an Extended Scale
Kiki A. Kurnia, Filipa Lima, Ana Filipa Cláudio, Joao A.P. Coutinho and Mara G. Freire
Physical Chemistry Chemical Physics 17 (2015) 18980--18990. DOI: 10.1039/C5CP03094C
The Effect of the Methylation and N-H Acidic Group on the Physicochemical Properties of Imidazolium-Based Ionic Liquids
Ana Sofia Moreira Conde Rodrigues , Marisa A. A. Rocha , Hugo Ferrão Dias Almeida , Catarina M. S. S. Neves , José A. Lopes da Silva , Mara G. Freire , Joao A.P. Coutinho and Luis M. N. B. F. Santos
Volumetric and Acoustical Properties of Aqueous Mixtures of N-methyl-2-hydroxyethylammonium Propionate at T = (298.15 to 333.15) K
Yang Li, Eduardo J.P. Figueiredo, Mário J.S.F. Santos, Jaime B. Santos, Nieves M.C. Talavera-Prieto, Pedro J. Carvalho, Abel G.M. Ferreira and Silvana Mattedi
Biochemical and Populational Responses Of An Aquatic Bioindicator Species, Daphnia longispina, To A Commercial Formulation Of A Herbicide
(Primextra® Gold TZ) And Its Active Ingredient (S-metolachlor)
M. Neves, B.B. Castro, T. Vidal, R. Vieira, J.C. Marques, J.A.P. Coutinho, F. Gonçalves and A.M.M. Gonçalves
Poly(vinyl alcohol) as a novel constituent to form aqueous two-phase systems with acetonitrile: Phase diagrams and partitioning experiments
Gustavo de Brito Cardoso, Isabela Nascimento Souza, Matheus M. Pereira, Luiz Pereira Costa, Mara G. Freire, Cleide Mara Faria Soaresa and Álvaro Silva Lima
Effect of the Cation on the Interactions between Alkyl Methyl Imidazolium Chloride Ionic Liquids and Water
Imran Khan, Mohamed Taha, Paulo Ribeiro-Claro, Simão P. Pinho and João A. P. Coutinho
The Journal of Physical Chemistry B 118 (2014) 10503–10514. DOI: 10.1021/jp5057495
Sustainable design for environment-friendly mono and dicationic cholinium-based ionic liquids
Francisca A. e Silva, Filipa Siopa, Bruna F.H.T. Figueiredo, Ana M.M. Gonçalves, Joana L. Pereira, Fernando Gonçalves, João A.P. Coutinho, Carlos A.M. Afonso and Sónia P.M. Ventura
Generating Ionic Liquids from Ionic Solids: An Investigation of the Melting Behavior of Binary Mixtures of Ionic Liquids
Guilherme J. Maximo, Ricardo J. B. N. Santos, Paula Brandão, José M. S. S. Esperança, Mariana C. Costa, Antonio J. A. Meirelles, Mara G. Freire and João A. P. Coutinho
The Impact of Ionic Liquids Fluorinated Moieties on Their Thermophysical Properties and Aqueous Phase Behaviour
Catarina M. S. S. Neves, Kiki A. Kurnia, Karina Shimizu, Isabel M. Marrucho, Luís Paulo N. Rebelo, João A.P. Coutinho, Mara G. Freire and José Nuno Canongia Lopes
Physical Chemistry Chemical Physics 16 (2014) 21340-21348. DOI: 10.1039/C4CP02008A
Ionic liquid Solutions as Extractive Solvents for Value-Added Compounds From Biomass
Helena Passos, Mara G. Freire and João A. P. Coutinho
Evaluation of the Conductor-like Screening Model for Real Solvents for the Prediction of the Water Activity Coefficient at Infinite Dilution in Ionic Liquids
Kiki A. Kurnia, Simão P. Pinho and João A. P. Coutinho
Industrial & Engineering Chemistry Research 53 (2014) 12466–12475. DOI: 10.1021/ie5021415
Thermophysical Properties of Sulfonium- and Ammonium-based Ionic Liquids
Arijit Bhattacharjee, Andreia Luís, João H. Santos, José A. Lopes-da-Silva, Mara G. Freire, Pedro J. Carvalho and João A.P. Coutinho
The Effect of the Cation Alkyl Chain Branching on Mutual Solubilities with Water and Toxicities
Kiki A. Kurnia, Tânia E. Sintra, Catarina M. S. S. Neves, Karina Shimizu, José N. Canongia Lopes, Fernando Gonçalves, Sónia P. M. Ventura, Mara G. Freire, Luís M. N. B. F. Santos and João A. P. Coutinho
Physical Chemistry Chemical Physics
16 (2014) 19952-19963. DOI: 10.1039/C4CP02309A
Ionic Liquid Recovery Alternatives in Ionic Liquid-based Three-phase Partitioning (ILTPP)
Enrique Alvarez-Guerra, Angel Irabien, Sónia P. M. Ventura and João A. P. Coutinho
Understanding Chemical Reactions of CO2 and its Isoelectronic Molecules with 1-butyl-3-methylimidazolium acetate by Changing the Nature of the Cation: The Case of CS2 in 1-butyl-1-methylpyrrolidinium acetate Studied by NMR Spectroscopy and Density Functional Theory Calculations
M. Isabel Cabaço, Marcel Besnard, Fabián Vaca Chávez, Noël Pinaud, Pedro J. Sebastião, João A. P. Coutinho and Yann Danten
The Journal of Chemical Physics 140 (2014) 244307. DOI: 10.1063/1.4884820
Trends and demands in solid-liquid equilibrium of lipidic mixtures
Guilherme José Maximo, Mariana Conceição Costa, João A.P. Coutinho and Antonio Meirelles
Cation alkyl side chain length and symmetry effects on the surface tension of ionic liquids
Hugo Ferrão Dias Almeida, Mara G. Freire, Ana Maria Fernandes, José A. Lopes da Silva, Pedro Morgado, Karina Shimizu, Eduardo J. M. Filipe, José N Canongia Lopes, Luís M. N. B. F. Santos and João A.P. Coutinho
Degradation of Imidazolium-based Ionic Liquids in Aqueous Solution by Fenton Oxidation
Carmen M. Domínguez1, Macarena Munoz, Asunción Quintanilla, Zahara M. de Pedro, Sonia P.M. Ventura, João A. P. Coutinho, Jose A. Casas and Juan J. Rodriguez
Journal of Chemical Technology and Biotechnology 89 (2014) 1197–1202. DOI: 10.1002/jctb.4366
Ionic Liquid-based Three Phase Partitioning (ILTPP) Systems: Ionic Liquid Recovery and Recycling
Enrique Alvarez-Guerra, Sónia P.M. Ventura, João A.P. Coutinho and Angel Irabien
Guilherme J. Maximo, Ricardo J. B. N. Santos, José A. Lopes-da-Silva, Mariana C. Costa, António J. A. Meirelles and João A. P. Coutinho
ACS Sustainable Chemistry & Energy 2 (2014) 672–682. DOI: 10.1021/sc400365h
Vapor-Liquid Equilibria of Water + Alkylimidazolium-based Ionic Liquids: Measurements and Perturbed-Chain Statistical Associating Fluid Theory Modeling
Helena Passos, Imran Khan, Fabrice Mutelet, Mariana B. Oliveira, Pedro Jorge Carvalho, Luis M. N. B. F. Santos, Christoph Held, Gabriele Sadowski, Mara G. Freire and Joao A.P. Coutinho
Industrial and Engineering Chemistry Research 53 (2014) 3737−3748. DOI: 10.1021/ie4041093
Understanding the Impact of the Central Atom on the Ionic Liquid Behavior: Phosphonium vs Ammonium Cations
Pedro J. Carvalho, Sónia P. M. Ventura, Marta L. S. Batista, Bernd Schröder, Fernando Gonçalves, José Esperança, Fabrice Mutelet and João A. P. Coutinho
The Journal of Chemical Physics 140 (2014) 064505. DOI: 10.1063/1.4864182
Molecular Interactions in Aqueous Biphasic Systems Composed of Polyethylene Glycol and Crystalline vs Liquid Cholinium-based Salts
Jorge Fernando Brandão Pereira, Kiki A Kurnia, O. Andreea Cojocaru, Gabriela Gurau, Luís Paulo N. Rebelo, Robin D. Rogers, Mara G Freire and Joao A.P. Coutinho
Measurement and Prediction of Speeds of Sound of Fatty Acid Ethyl Esters and Ethylic Biodiesels
Samuel V. D. Freitas, Ângela Santos, Maria-Luísa C. J. Moita, Luis A. Follegatti-Romero, Telma P. V. B. Dias, Antonio J. A. Meirelles, Jean-Luc Daridon, Álvaro S. Lima and João A. P. Coutinho
Imidazolium and Pyridinium Ionic Liquids from Mandelic Acid Derivatives: Synthesis and Bacteria and Algae Toxicity Evaluation
Sónia P. M. Ventura, Monika Gurbisz, Mukund Ghavre, Fábio M. M. Ferreira, Fernando Gonçalves, Ian Beadham, Brid Quilty, João A. P. Coutinho and Nicholas Gathergood
Protic Ionic Liquid as Additive on Lipase Immobilization using Silica Sol–Gel
Ranyere Lucena de Souza, Emanuelle Lima Pache de Faria, Renan Tavares Figueiredo, Lisiane dos Santos Freitas, Miguel Iglesias, Silvana Mattedi, Gisella Maria Zanin, Onélia Aparecida Andreo dos Santos, João A. P. Coutinho, Álvaro Silva Lima and Cleide Mara Faria Soares
Novel Data and a Group Contribution Method for the Prediction of the Speed of Sound and Isentropic Compressibility of Pure Fatty Acids Methyl and Ethyl Esters
Jean-Luc Daridon, João A. P. Coutinho, El Hadji Ibrahim Ndiaye and Márcio L.L. Paredes
Surface Tension of Binary Mixtures of 1-Alkyl-3-Methylimidazolium Bis(trifluoromethylsulfonyl)imide Ionic Liquids: Experimental Measurements and Soft-SAFT Modeling
Mariana B. Oliveira, Montserrat Domínguez-Pérez, Mara G. Freire, Felix Llovell, Oscar Cabeza, José A. Lopes da Silva, Lourdes F Vega and João A. P. Coutinho
The Journal of Physical Chemistry B 116 (2012) 12133–12141. DOI: 10.1021/jp3059905
Increased Significance of Food Wastes: Selective Recovery of Added-value Compounds
Igor A.O. Reis, Samuel B. Santos, Ludmila A. Santos, Naiana Oliveira, Mara G. Freire, Jorge F. B. Pereira, Sónia P. M. Ventura, João A. P. Coutinho, Cleide M. F. Soares and Álvaro S. Lima
Characterization by Electrospray Ionization and Tandem Mass Spectrometry of Rhamnolipids Produced by Two Pseudomonas Aeruginosa Strains Isolated from Brazilian Crude Oil
Jorge F.B. Pereira, Eduardo J. Gudiña, M. Luísa Dória, M. Rosário Domingues, Lígia R. Rodrigues, José A. Teixeira and João A. P. Coutinho
European Journal of Mass Spectrometry 18 (2012) 399–406. DOI: 10.1255/ejms.1194
Vapor–Liquid Equilibrium, Densities, and Interfacial Tensions of the System Hexane + 2,5-Dimethylfuran
Andrés Mejía, Hugo Segura, Marcela Cartes and João A. P. Coutinho
Journal of Chemical and Engineering Data 57 (2012) 2681–2688. DOI: 10.1021/je300631s
Cation Symmetry effect on the Volatility of Ionic Liquids
Marisa A. A. Rocha, João A. P. Coutinho and Luís M. N. B. F. Santos
The Journal of Physical Chemistry B 116 (2012) 10922–10927. DOI: 10.1021/jp306937f
Ionic-liquid-based Aqueous Biphasic Systems for Improved Detection of Bisphenol A in Human Fluids
Helena Passos, Ana C. A. Sousa, M. Ramiro Pastorinho, António J. A. Nogueira, Luís Paulo N. Rebelo, João A. P. Coutinho and Mara G. Freire
Overview of the Liquid–Liquid Equilibria of Ternary Systems Composed of Ionic Liquid and Aromatic and Aliphatic Hydrocarbons, and Their Modeling by COSMO-RS
Ana R. Ferreira, Mara G. Freire, Jorge C. Ribeiro, Fernando M. Lopes, João G. Crespo and João A. P. Coutinho
Industrial and Engineering Chemistry Research 51 (2012) 3483-3507. DOI: 10.1021/ie2025322
Liquid–liquid Equilibria for Ethyl Esters + Ethanol + Water Systems: Experimental Measurements and CPA EoS Modeling
Luis A. Follegatti-Romero, Mariana B. Oliveira, Eduardo A. C. Batista, João A. P. Coutinho and Antonio J. A. Meirelles
Insight into the Interactions That Control the Phase Behaviour of New Aqueous Biphasic Systems Composed of Polyethylene Glycol Polymers and Ionic Liquids
Mara G. Freire, Jorge F. B. Pereira, María Francisco, Héctor Rodríguez, Luís Paulo N. Rebelo, Robin D. Rogers and João A. P. Coutinho
Ionic Liquid Based Aqueous Biphasic Systems with Controlled pH: The Ionic Liquid Cation Effect
Sónia P. M. Ventura, Sílvia G. Sousa, Luísa S. Serafim, Álvaro S. Lima, Mara G. Freire and João A. P. Coutinho
Journal of Chemical & Engineering Data 56 (2011) 4253–4260. DOI: 10.1021/je200714h
Chameleonic Behavior of Ionic Liquids and Its Impact on the Estimation of Solubility Parameters
Marta L. S. Batista, Catarina M. S. S. Neves, Pedro J. Carvalho, Rafiqul Gani and João A. P. Coutinho
Journal of Physical Chemistry B 115 (2011) 12879-12888. DOI: 10.1021/jp207369g
Thermophysical Characterization of Ionic Liquids Able To Dissolve Biomass
Mara G. Freire, Ana Rita R. Teles, Marisa A. A. Rocha, Bernd Schröder, Catarina M. S. S. Neves, Pedro J. Carvalho, Dmitry V. Evtuguin, Luís M. N. B. F. Santos, and João A. P. Coutinho
Journal of Chemical & Engineering Data 56 (2011) 4813-4822. DOI: 10.1021/je200790q
Measurement and Prediction of Biodiesel Surface Tensions
Samuel Venancio de Sousa Freitas , Mariana B. Oliveira , António J. Queimada , Maria Jorge Pratas , Álvaro Silva Lima and João A. P. Coutinho
The Polarity Effect Upon the Methane Solubility in Ionic Liquids: A Contribution For the Design of Ionic Liquids For Enhanced CO2/CH4 and H2S/CH4 Selectivities
Pedro J. Carvalho and João A. P. Coutinho
Energy & Environmental Science 4 (2011) 4614-4619. DOI: 10.1039/c1ee01599k
High-Accuracy Vapor Pressure Data of the Extended [CnC1im][NTf2] Ionic Liquid Series: Trend Changes and Structural Shifts
Marisa A. A. Rocha, Carlos F. R. A. C. Lima, Lígia R. Gomes, Bernd Schröder, João A. P. Coutinho, Isabel M. Marrucho, José M. S. S. Esperança, Luís P. N. Rebelo, Karina Shimizu, José N. Canongia Lopes and Luís M. N. B. F. Santos
The Journal of Physical Chemistry B 115 (2011) 10919-10926. DOI: 10.1021/jp2049316
Critical Assessment of the Formation of Ionic-Liquid-Based Aqueous Two-Phase Systems in Acidic Media
Ana Filipa M. Cláudio, Ana M. Ferreira, Shahla Shahriari, Mara G. Freire and João A. P. Coutinho
The Journal of Physical Chemistry B 115 (2011) 11145-11153. DOI: 10.1021/jp204865a
Design of Ionic Liquids for Lipase Purification
Sónia P. M. Ventura, Sílvia G. Sousa, Mara G. Freire, Luísa S. Serafim, Álvaro S. Lima and João A. P. Coutinho
Aqueous Solubility, Effects of Salts on Aqueous Solubility, and Partitioning Behavior of Hexafluorobenzene: Experimental Results and COSMO-RS Predictions
Bernd Schröder, Mara G. Freire, Fatima R. Varanda, Isabel M. Marrucho, Luís M. N. B. F. Santos, João A. P. Coutinho
An Overview of the Liquid-Liquid Equilibria of (Ionic Liquid + Hydrocarbon) Binary Systems and Their Modeling by the Conductor-like Screening Model for Real Solvents
Ana R. Ferreira, Mara G. Freire, Jorge C. Ribeiro, Fernando M. Lopes, João G. Crespo and João A. P. Coutinho
Industrial & Engineering Chemistry Research 50 (2011) 5279–5294. DOI: 10.1021/ie102471b
Separation of Ethanol-Water Mixtures by Liquid-Liquid Extraction using Phosphonium-based Ionic Liquids
Catarina M.S.S. Neves, José F.O. Granjo, Mara G. Freire, Al Robertson, Nuno M. C. Oliveira and João A. P. Coutinho
Modeling Phase Equilibria Relevant to Biodiesel Production: A Comparison of gE Models, Cubic EoS, EoS-gE and Association EoS
Mariana B. Oliveira, Vítor Ribeiro, António Jos Queimada and João A. P. Coutinho
Industrial & Engineering Chemistry Research 50 (2011) 2348-2359. DOI: 10.1021/ie1013585
Supported Ionic Liquid Silica Nanoparticles (SILnPs) as an Efficient and Recyclable Heterogeneous Catalyst for the Dehydration of Fructose to 5-hydroxymethylfurfural
Kalpesh B. Sidhpuria, Ana L. Daniel-da-Silva, Tito Trindade and João A. P. Coutinho
Mass Spectrometric Studies on Ionic Liquid Aggregates
R. Lopes da Silva, Isabel M. Marrucho, João A. P. Coutinho and Ana M. Fernandes
Chapter 4: Molten Salts and Ionic Liquids: Never the Twain? Edited by Marcelle Gaune-Escard and Kenneth R. Seddon, John Wiley & Sons, Inc. (2010) 49-61
Toward an Understanding of the Aqueous Solubility of Amino Acids in the Presence of Salts: A Molecular Dynamics Simulation Study
Luciana I. N. Tomé, Miguel Jorge, Jose R. B. Gomes and João A. P. Coutinho
Journal of Physical Chemistry B 114 (2010) 16450-16459. DOI: 10.1021/jp104626w
Liquid-Liquid Equilibrium for Ternary Systems Containing Ethyl Esters, Anhydrous Ethanol and Water at 298.15, 313.15, and 333.15 K
Luis A. Follegatti-Romero, Marcelo Lanza, Fabio R. M. Batista, Eduardo A. C. Batista, Mariana B. Oliveira, João A. P. Coutinho and Antonio J. A. Meirelles
Industrial & Engineering Chemistry Research 49 (2010) 12613-12619. DOI: 10.1021/ie101611j
Mutual Solubility of Water and Structural/Positional Isomers of N-Alkylpyridinium-Based Ionic Liquids
Mara G. Freire, Catarina M. S. S. Neves, Karina Shimizu, Carlos E. S. Bernardes, Isabel M. Marrucho, João A. P. Coutinho, José N. Canongia Lopes and Luís Paulo N. Rebelo
Journal of Physical Chemistry B 114 (2010) 15925-15934. DOI: 10.1021/jp1093788
Non-ideality of Solutions of NH3, SO2, and H2S in Ionic Liquids and the Prediction of their Solubilities using the Flory-Huggins Model
Thermophysical Properties and Water Saturation of [PF6]-Based Ionic Liquids
Catarina M. S. S. Neves, Marta L. S. Batista, Ana Filipa M. Cláudio, Luís M. N. B. F. Santos, Isabel M. Marrucho, Mara G. Freire and João A. P. Coutinho
Journal of Chemical & Engineering Data 55 (2010) 5065-5073. DOI: 10.1021/je100638g
Densities and Viscosities of Fatty Acid Methyl and Ethyl Esters
Maria Jorge Pratas, Samuel Freitas, Mariana B. Oliveira, Sílvia C. Monteiro, Alvaro S. Lima and João A. P. Coutinho
Journal of Chemical & Engineering Data 55 (2010) 3983-3990. DOI: 10.1021/je100042c
Structural and Positional Isomerism Influence in the Physical Properties of Pyridinium NTf2-Based Ionic Liquids: Pure and Water-Saturated Mixtures
Filipe S. Oliveira, Mara G. Freire, Pedro J. Carvalho, João A. P. Coutinho, Jose N. Canongia Lopes, Luis P. N. Rebelo and Isabel M. Marrucho
Journal of Chemical & Engineering Data 55 (2010) 4514–4520. DOI: 10.1021/je100377k
Poly(lactic acid): Synthesis, Structures, Properties, Processing, and Applications
Carla M. B. Gonçalves, João A. P. Coutinho and Isabel M. Marrucho
Chapter 8: Optical Properties. Edited by Rafael Auras, Loong-Tak Lim, Susan E. M. Selke and Hideto Tsuji, John Wiley & Sons, Inc. (2010) 97 - 112.
Characterization of Libyan Waxy Crude Oils
Layla M. Alghanduri, Mohamed M. Elgarni, Jean-Luc Daridon and Joao A. P. Coutinho
1H NMR and Molecular Dynamics Evidence for an Unexpected Interaction on the Origin of Salting-In/Salting-Out Phenomena
Mara G. Freire, Catarina M. S. S. Neves, Artur M. S. Silva, Luís M. N. B. F. Santos, Isabel M. Marrucho, Luís P. N. Rebelo, Jindal K. Shah, Edward J. Maginn and João A. P. Coutinho
Journal of Physical Chemistry B 114 (2010) 2004-2014. DOI: 10.1021/jp9095634
Solubility of Non-aromatic Ionic Liquids in Water and Correlation Using a QSPR Approach
Mara G. Freire, Catarina M.S.S. Neves, Sónia P.M. Ventura, Maria J. Pratas, Isabel M. Marrucho, João Oliveira, João A.P. Coutinho and Ana M. Fernandes
Modeling of Biodiesel Multicomponent Systems with the Cubic-Plus-Association (CPA) Equation of State
Mariana B. Oliveira, António J. Queimada and João A. P. Coutinho
Industrial & Engineering Chemistry Research 49 (2010) 1419-1427. DOI: 10.1021/ie901264d
Predicting the Thermodynamic Behavior of Water & Ionic Liquids Systems Using COSMO-RS
Mara G. Freire, Luís M. N. B. F. Santos, Isabel M. Marrucho and João A. P. Coutinho
Chapter 8 Molten Salts and Ionic Liquids: Never the Twain? Edited by Marcelle Gaune-Escard and Kenneth R. Seddon, John Wiley & Sons, Inc. (2010) 101-121
Hydrolysis of Tetrafluoroborate and Hexafluorophosphate Counter Ions in Imidazolium-Based Ionic Liquids
Mara G. Freire, Catarina M. S. S. Neves, Isabel M. Marrucho, João A. P. Coutinho and Ana M. Fernandes
Journal of Physical Chemistry A 114 (2010) 3744-3749. DOI: 10.1021/jp903292n
Solubility of Adamantane in Phosphonium-Based Ionic Liquids
Filipe S. Oliveira, Mara G. Freire, Maria J. Pratas, Jérôme Pauly, Jean L. Daridon, Isabel M. Marrucho and João A. P. Coutinho
Journal of Chemical & Engineering Data 55 (2010) 662-665. DOI: 10.1021/je9006772
Effect of Water on the Viscosities and Densities of 1-Butyl-3-methylimidazolium Dicyanamide and 1-Butyl-3-methylimidazolium Tricyanomethane at Atmospheric Pressure
Pedro J. Carvalho, Teresa Regueira, Luis M. N. B. F. Santos, Josefa Fernandez, João A. P. Coutinho
Journal of Chemical & Engineering Data 55 (2010) 645-652. DOI: 10.1021/je900632q
Solubility of Water in Fluorocarbons: Experimental and COSMO-RS Prediction Results
Mara G. Freire, Pedro J. Carvalho, Luís M.N.B.F. Santos, Lígia R. Gomes, Isabel M. Marrucho and João A.P. Coutinho
Thermodynamic Characterization of Pure Perfluoroalkanes, including Interfacial and Second Order Derivative Properties, using the Crossover Soft-SAFT EoS
A. M. A. Dias, F. Llovell, J. A. P. Coutinho, I. M. Marrucho, L. F. Vega
On the Interactions between Amino Acids and Ionic Liquids in Aqueous Media
Luciana I. N. Tome, Montserrat Domínguez-Perez, Ana Filipa M. Claudio, Mara G. Freire, Isabel M. Marrucho, Oscar Cabeza and João A. P. Coutinho
Journal of Physical Chemistry B 113 (2009) 13971-13979. DOI: 10.1021/jp906481m
Crystallization Behavior of Mixtures of Fatty Acid Ethyl Esters with Ethyl Stearate
L. Boros, M. L. S. Batista, Raquel V. Vaz, B. R. Figueiredo, V. F. S. Fernandes, M. C. Costa, M. A. Krahenbuhl, A. J. A. Meirelles and J. A. P. Coutinho
High Pressure Phase Behavior of Carbon Dioxide in 1-Butyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide and 1-Butyl-3-methylimidazolium Dicyanamide Ionic Liquids
Pedro J. Carvalho, Víctor H. Álvarez, Isabel M. Marrucho, Martín Aznar and João A.P. Coutinho
Gas-Phase Dissociation of Ionic Liquids Aggregates Studied by Electrospray Ionization Mass Spectrometry and Energy-Variable Collision Induced Dissociation
Ana M. Fernandes, João A. P. Coutinho and Isabel M. Marrucho
Journal of Mass Spectrometry 44 (2009) 144-150. DOI: 10.1002/jms.1484
Towards an understanding of the mutual solubilities of water and hydrophobic ionic liquids in the presence of salts: The anion effect
Luciana I. N Tomé, Fatima R. Varanda, Mara G. Freire, Isabel M. Marrucho and João A. P. Coutinho
Journal of Physical Chemistry B 113 (2009) 2815-2825. DOI: 10.1021/jp810141d
Ion Specific Effects on the Mutual Solubilities of Water and Hydrophobic Ionic Liquids
Mara G. Freire, Pedro J. Carvalho, Artur M. S. Silva, Luís M. N. B. F. Santos, Luís P. N. Rebelo, Isabel M. Marrucho and João A. P. Coutinho
Journal of Physical Chemistry B 113 (2009) 202-211. DOI: 10.1021/jp8080035
The Solid-Liquid Phase Diagrams of Binary Mixtures of Consecutive, even Saturated Fatty Acids: Differing by Four Carbon Atoms
Mariana C. Costa, Mariana Sardo, Marlus P. Rolemberg, Paulo Ribeiro-Claro, Antonio J.A. Meirelles, João A.P. Coutinho, M. A. Krähenbühl
Solubility of Water in Tetradecyltrihexylphosphonium-based Ionic Liquids
Mara G. Freire, Pedro J. Carvalho, Ramesh L. Gardas, Luís M.N.B.F. Santos, Isabel Marrucho, João A. P. Coutinho
Journal of Chemical & Engineering Data 53 (2008) 2378-2382. DOI: 10.1021/je8002805
Solubility of Antibiotics in Different Solvents. Part II: Non-Hydrochloride Forms of Tetracycline and Ciprofloxacin
Ana Caço, Fatima Varanda, Maria Jorge Pratas de Melo, Ana dias, Ralf Dohrn, Isabel Marrucho
Industrial & Engineering Chemistry Research 47 (2008) 8083-8089. DOI: 10.1021/ie8003495
A Group Contribution Method for Heat capacity Estimation of Ionic Liquids
Ramesh L. Gardas, João A. P. Coutinho
Industrial & Engineering Chemistry Research 47 (2008) 5751-5757. DOI: 10.1021/ie800330v
Measurements and Correlation of High Pressure Densities of Imidazolium Based Ionic Liquids
Luciana I. N. Tomé, Pedro J. Carvalho, Mara G. Freire, Isabel M. Marrucho, Isabel M. A. Fonseca, Abel G. M. Ferreira, João A. P. Coutinho, Ramesh L. Gardas
Journal of Chemical & Engineering Data 53 (2008) 1914-1921. DOI: 10.1021/je800316b
High Pressure Solubility Data of Carbon Dioxide in Tri-iso-butyl(methyl)phosphonium Tosylate - Water Systems
Sónia P. M. Ventura, Jérôme Pauly, Jean L. Daridon, J. A. Lopes da Silva, Isabel M. Marrucho, Ana. M. A. Dias and João A. P. Coutinho
Densities and Derived Thermodynamic Properties of Imidazolium-, Pyridinium-, Pyrrolidinium-, and Piperidinium- Based Ionic Liquids
Ramesh L. Gardas, Henrique F. Costa, Mara G. Freire, Pedro J. Carvalho, Isabel M. Marrucho, Isabel M. A. Fonseca, Abel G. M. Ferreira, João A. P. Coutinho
Journal of Chemical & Engineering Data 53 (2008) 805-811. DOI: 10.1021/je700670k
Thermodynamic Studies of Ionic Interactions in Aqueous Solutions of Imidazolium Based Ionic Liquids [Emim][Br] and [Bmim][Cl]
Ramesh L. Gardas, Dilip H. Dagade, João A. P. Coutinho, Kesharsingh J. Patil
The Journal of Physical Chemistry 112 (2008) 3380-3389. DOI: 10.1021/jp710351q
Applying a QSPR Correlation to the Prediction of Surface Tensions of Ionic Liquids
Preparation and characterization of organosilicon thin films for selective adhesion of Yarrowia lipolytica yeast cells
Marian Lehocky, Priscilla Filomena Fonseca Amaral, Pavel St’ahel, Maria Alice Zarur Coelho, Ana Margarida Barros-Timmons and João Araujo Pereira Coutinho
Journal of Chemical Technology and Biotechnology 82 (2007) 360-366. DOI: 10.1002/jctb.1677
Analysis of the Isothermal Structure Development in Waxy Crude Oils under Quiescent Conditions
Mutual Solubilities of Water and Hydrophobic Ionic Liquids
Mara G. Freire, Catarina M. S. S. Neves, Pedro J. Carvalho, Ramesh L. Gardas, Ana M. Fernandes, Isabel M. Marrucho, Luis M. N. B. F. Santos and João A. P. Coutinho
Journal of Physical Chemistry B 111 (45) (2007) 13082-13089. DOI: 10.1021/jp076271e
Total mercury in sediments from mud volcanoes in Gulf of Cadiz
C.L. Mieiro, P. Pato, E. Pereira, F. Mirante, J.A.P. Coutinho, L.M. Pinheiro, V.H. Magalhaes, A.C. Duarte
Binary interaction parameters for nonpolar systems with cubic equations of state: a theoretical approach. 1. CO2/hydrocarbons using SRK equation of state.
J. A. P. Coutinho, G. M. Kontogeorgis and E. H. Stenby
